Economic analysis of hydrogen production from steam. K and higher water ethanol ratios, the desired reaction of ethanol steam reforming reaction can be predominated 2. Ethanol steam reforming is more complicated than msr. Steam reforming of bioethanol over ni on cezro support.
This is an important consideration for the improved heat integration of fuel cell vehicles. Realization of ethanol steam reforming at high temperature leads to an increase in efficiency of the process. A simple algorithm was purposed to rationalize et al. Mechanistic aspects of the steam reforming of ethanol reaction. Hydrogen production via steam reforming of ethyl alcohol. Energy analysis of ethanol steam reforming for hybrid. Sustainable hydrogen production by catalytic bioethanol. The bio ethanol steam reforming over nickelbased catalysts when the temperature is within the range of 700 to 800 k is studied for fuel cell applications. Muhammad bilal 1, claire gillan, sam french2, martin fowles2 and s david jackson1 1centre for catalysis research, westchem, university of glasgow, glasgow g12 8qq, scotland, uk 2johnson matthey plc, belasis ave, billingham ts23 1lb uk.
Numerical investigations are conducted to analyze energy performance of steam reforming of ethanol for ice. Because of their high activity and low cost, cobased and nibased catalysts are suitable for industrial esr processes. More importantly, ethanol is co2 neutral since the amount of co2 produced by steam reforming is consumed by the biomass growth. Zvirin faculty of mechanical engineering, technionisrael institute of technology, 32000, technion city, haifa, israel summary thermodynamic equilibrium of ethanol steam reforming is studied using the gibbs free energy minimization. Renewable hydrogen from ethanol by autothermal reforming. Kinetics, catalysis and mechanism of methane steam reforming. Mechanistic kinetic models for steam reforming of concentrated crude. Ethanol steam reforming esr proceeds at temperatures in the range of 300600 c, which is signi. The results show that the introduction of mgo effectively increases the dispersion of cao via forming mgcaco 3 2 precursor.
Heterogeneous catalysis research group department of chemical and biomolecular engineering the ohio state university columbus, oh 43210 ozkan. The steam reforming of ethanol has been widely investigated over several catalytic materials. Deactivation, related to carbonaceous compounds deposition, is considered the principal inconvenience of the catalytic. Ethanol steam reforming esr is a promising reaction as a sustainable, carbonneutral hydrogen production process. Pdf new catalysts for hydrogen production by steam reforming of bioethanol have been developed. Silicasupported bimetallic cocu composite an efficient. Molecular catalysis for the steam reforming of ethanol. Cfd simulation of ethanol steam reforming system for.
The reaction studied is the ethanol steam reforming esr reaction. Several simultaneous side reactions occur during the main reaction. Studies of the ethanol steam reforming reaction in a membrane reactor hankwon lim abstract the subject of this dissertation is advanced inorganic membranes and their application in membrane reactors mrs. The effects of process variables, such as temperature and water. Hydrogen production by catalytic ethanol steam reforming. Steam reforming of methanol, ethanol and glycerol over. Hydrogen production by the steam reforming of bioethanol. In last two decades research interest in the area of catalytic steam reforming of ethanol has been increased. Results proved that ni incorporated mcm41 type catalytic materials were highly active in hydrogen production by steam reforming of ethanol and. The effect of operating conditions such as the temperature, space time, waterto ethanol molar ratio, and oxygento ethanol molar ratio on the product distribution is evaluated. Different c3 functional group impurities were added individually to the pure ethanol to investigate the influence of different functional groups on the ethanol steam reforming reaction over 0.
Microkinetics of alcohol reforming for h 2 production from. In the steam reforming sr process, ethanol, sugars, and other oxygenated compounds react on metals and oxides with steam at temperatures around 4001100 k. Steam reforming of ethane and ethanol over rhalumina. Hydrogen production by ethanol steam reforming on ni. These excellent ethanol reforming performances of nicezro2 in terms of.
Based on the reported composition of the crude ethanol 1, a typical reactant liquid mixture is assumed to be composed of 1% glycerol, 1% lactic acid, 12% ethanol, and 86% water at volumetric percentage. Impact of bioethanol impurities on steam reforming for. The watergas shift reaction is examined in the reforming process. The generation of the saturated ethanol vapor or water vapor was achieved by passing he through a bubbler filled with pure ethanol or deionized water. Hydrogen production from steam reforming of ethanol over an. Because hydrogen needs within various sectors of the cpi are at their highest levels in history, and are continuing to grow, an understanding of this method of hydrogen production and purification can be useful. One of the most interesting routes to produce energy from biomass is the production of hydrogen by bio ethanol steam reforming. Coke formation over the catalyst surface is the main drawback in esr.
Therdthianwong a et al6 are the early group who worked on the ethanol steam reforming over nial 2 o 3 catalyst in a fixed bed reactor by studying the influence of temperature, steam to carbon ratio and feed rate of dilute ethanol solution on steam reforming reaction. The palladiumindium oxide catalyst shows higher hydrogen production rate than indium oxide and palladium. The main purpose of this technology is hydrogen production. Energy analysis of ethanol steam reforming for hybrid electric vehicle l. Basic thermodynamic data on the effect of the conditions of steam reforming of ethanol as a prospective method for the production of hydrogen from renewable raw material on the equilibrium yield. Recent progress in ethanol steam reforming using nonnoble transition metal catalysts. Hydrogen fuel cells h2fcs are promising devices for pollutionfree and efficient power production.
Investigation of bioethanol steam reforming over cobalt. Palladiumindium oxide affords ketonization of ethyl alcohol with negligible byproduct carbon monoxide, while indium oxide mainly affords. Production of synthesis gases from ethanol steam reforming. Ethanol steam reforming does not require supplemental fuel gas consumption as in the traditional process scheme for which the fuel gas accounts for 15 20% of total firing for controllability purposes. Various authors have tried to perform a thermodynamic analysis of the ethanol steam reforming reaction, concluding that high temperature, together with a high waterto ethanol molar ratio and low pressure are necessary to promote selectivity towards hydrogen instead of byproducts formation 1820. Further, besides being more safe and easier to handle, steam reforming of ethanol occurs at comparatively lower temperature compared to other fuels 5,6. Stable hydrogen production from ethanol through steam. The bio ethanol produced by fermentation of biomass can yield an ethanol water mixture already ideal for reforming without additional distillation steps.
Controllability study of an ethanol steam reforming. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. Pdf production of hydrogen by steam reforming of ethanol. Page 1 steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. The gas flow rate used in this study, 10 ccmin, was sufficiently low to guarantee that the. The main fuel for the steam reformer furnace is the tail gas from. Using hydrous ethanol has a practical advantage for onboard reforming because it contains the necessary water for the sr reaction. The mechanism of steam reforming of higher hydrocarbons is more complex. Model for steam reforming of ethanol using a catalytic. Ethanol steam reforming esr on a group of multifunctional xfeycu10nibeta catalysts was studied using in xray diffraction xrd, scanning electron microscopy coupled with energydispersive spectroscopy semeds, temperatureprogrammed reduction in hydrogen h2tpr, temperatureprogrammed oxidation tpo, and xray absorption fine structure xafs techniques with a focus on. Investigation of bio ethanol steam reforming over cobaltbased catalysts. Both reactants water and ethanol contain h atoms which contribute to the hydrogen yield and, furthermore, ethanol is nontoxic and easy to. The reaction is strongly endothermic consumes heat. The test reaction was ethanol steam reforming carried out at a temperature interval of 250c750c and a ratio h2oc2h5oh of 31.
Ethanol steam reforming ethanol steam reforming is the cheapest and most efficient way to produce hydrogen from biomass. Production of hydrogen by steam reforming of ethanol has been performed using different catalytic systems. Recent progress in ethanol steam reforming using nonnoble. Model for steam reforming of ethanol using a catalytic wall reactor j. Introduction energy is an essential input for social development and economic growth. The activity of catalysts depends on several factors such as the nature of the active metal catalyst and the catalyst support, the precursor used, the method adopted for catalyst preparation, and the presence of. We report the synergetic effect between palladium and indium oxide on hydrogen production in the steam reforming reaction of ethyl alcohol. Pdf on jan 1, 2017, laura soares and others published overview of the ethanol steam reforming for hydrogen. Steam reforming of ethanol for producing hydrogen gas is a promising means since ethanol can readily be obtained through biomass fermentation. Steam reforming of bio ethanol over ni on cezro 2 support singhto, w. Low temperatureethanol steam reforming over nibased. Hydrogen production from ethanol through steam reforming solves issues involved in hydrogen storage and infrastructure and lends itself very well to a distributed hydrogen production strategy.
Pdf hydrogen production by steam reforming of ethanol. The current dependence on fossil fuels and issues related to climate change have. Studies of the ethanol steam reforming reaction in a. The coceo 2 catalyst displayed excellent reforming performance as shown in figure 1. Hydrogen production from ethanol for fuel cell applications. In esr also, catalyst activity and reaction conditions are the main controlling parameters to reduce the side products. These excellent ethanol reforming performances of nicezro 2 in terms of stability, reactivity and product selectivities are due to the high redox property of cezro 2. Steam reforming is most widely used to generate hydrogen not only with nonrenewable fossil fuels coal, natural gas, petroleum but also with renewable raw materials such as ethanol. This article describes the design and synthesis of mgo. Renewable h2 from biomass is often produced through catalytic ethanol steam reforming esr, which requires a steam ethanol molar ratio of at least three. In this research the rate expression for the ethanol steam reforming reaction at 400 and. This is an important consideration for the improved heat integration of. Efficient hydrogen production from ethanol steam reforming over layercontrolled grapheneencapsulated ni catalysts.
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